Green Synthesis of Nickel Oxide Nanoparticles and its Application in the Degradation of Methyl Red
DOI:
https://doi.org/10.62050/ljsir2024.v2n2.328Keywords:
Green synthesis, NiO nanoparticles, Azo dye, FTIR, SEMAbstract
Environmental pollution is a threat to human health, with methyl red dye used in printing and textile dyeing being a notable pollutant that can cause eye, skin, and digestive system irritation. This study investigates the degradation of methyl red dye using nanoparticles of Nickel Oxide (NiO NPs) as photocatalysts. NiO NPs were synthesised at room temperature through thermal decomposition using antioxidant-rich extracts from strawberries (Fragaria ananassa), grapes (Vitis vinifera), and grapefruits (Citrus paradisi). Characterisation of the NiO NPs was performed using FTIR, UV-Vis spectroscopy and SEM. FTIR spectra confirmed the formation of NiO NPs with peaks between 577 – 585 cm–1. UV-Vis spectroscopy showed absorption wavelengths between 322-326 nm for the synthesised NiO NPs and a blue shift to 422-470 nm during methyl red degradation. This study presents a sustainable method for synthesising NiO nanoparticles and demonstrates their effectiveness in environmental remediation, specifically for the removal of pollutant dyes.
Downloads
References
S. Sagadevan, I. Fatimah, J. A. Lett, M. Z. Rahman, E. Leonard, W.-C. Oh, Eco-friendly green approach of nickel oxide nanoparticles for biomedical applications, Open Chemistry. 21 (2023). https://doi.org/10.1515/chem-2023-0141.
R.S. Kate, S.A. Khalate, R.J. Deokate, Overview of nanostructured metal oxides and pure nickel oxide (NiO) electrodes for supercapacitors: A review, Journal of Alloys and Compounds. 734 (2018) 89–111. https://doi.org/10.1016/j.jallcom.2017.10.262.
A. Singh, V. Goyal, J. Singh, H. Kaur, S. Kumar, K.M. Batoo, J. Gaur, M. Pal, M. Rawat, S. Hussain, Structurally and morphologically engineered single-pot biogenic synthesis of NiO nanoparticles with enhanced photocatalytic and antimicrobial activities, Journal of Cleaner Production. 343 (2022) 131026. https://doi.org/10.1016/j.jclepro.2022.131026.
P. Kathiravan, K. Thillaivelavan, G. Viruthagiri, N. Shanmugam, Investigations of thermal, structural, optical, morphological and magnetic properties of chemical precipitation synthesized NiO nanoparticles for optoelectronic applications, Journal of the Indian Chemical Society. (2024) 101171–101171. https://doi.org/10.1016/j.jics.2024.101171.
A. Gandhi, S. Wu, Strong Deep-Level-Emission Photoluminescence in NiO Nanoparticles, Nanomaterials. 7 (2017) 231–231. https://doi.org/10.3390/nano7080231.
A. Kumar Rai, L. Tuan Anh, C.-J. Park, J. Kim, Electrochemical study of NiO nanoparticles electrode for application in rechargeable lithium-ion batteries, Ceramics International. 39 (2013) 6611–6618. https://doi.org/10.1016/j.ceramint.2013.01.097.
V. Biju, M. Abdul Khadar, DC conductivity of consolidated nanoparticles of NiO, Materials Research Bulletin. 36 (2001) 21–33. https://doi.org/10.1016/s0025-5408(01)00488-3.
T. Ali, M.F. Warsi, S. Zulfiqar, A. Sami, S. Ullah, A. Rasheed, I.A. Alsafari, P.O. Agboola, I. Shakir, M.M. Baig, Green nickel/nickel oxide nanoparticles for prospective antibacterial and environmental remediation applications, Ceramics International. 48 (2022) 8331–8340. https://doi.org/10.1016/j.ceramint.2021.12.039.
N. Venkatalakshmi, H. Jyothi Kini, H.S. Bhojya Naik, Green-synthesized Nickel oxide nanoparticles: Magnetic and Biomedical applications, Inorganic Chemistry Communications. (2023) 110490. https://doi.org/10.1016/j.inoche.2023.110490.
H.L. Karlsson, M.S. Toprak, Bengt Fadeel, Toxicity of metal and metal oxide nanoparticles, Elsevier EBooks. (2022) 87–126. https://doi.org/10.1016/b978-0-12-823292-7.00002-4.
A.A. Ezhilarasi, J.J. Vijaya, K. Kaviyarasu, M. Maaza, A. Ayeshamariam, L.J. Kennedy, Green synthesis of NiO nanoparticles using Moringa oleifera extract and their biomedical applications: Cytotoxicity effect of nanoparticles against HT-29 cancer cells, Journal of Photochemistry and Photobiology B: Biology. 164 (2016) 352–360. https://doi.org/10.1016/j.jphotobiol.2016.10.003.
M. Alagiri, S. Ponnusamy, C. Muthamizhchelvan, Synthesis and characterization of NiO nanoparticles by sol–gel method, Journal of Materials Science: Materials in Electronics. 23 (2011) 728–732. https://doi.org/10.1007/s10854-011-0479-6.
A.A.A. Ahmed, S.A. Issa, S.A. Al-Marbie, M.A. Al-Geraei, H.A. Al-Mtouakell, S.A. Al-Mangathi, J.M. Abduljaleel, A.A. Qaid, Structural, optical and antibacterial characteristics of CdO nanostructure prepared via simple method, Albaydha University Journal. 2 (2020) 16–24. https://doi.org/10.56807/buj.v2i2.51.
B. T. Sone, Physical & Electrochemical Properties of Green Synthesized Bunsenite NiO Nanoparticles via Callistemon Viminalis’ Extracts, International Journal of Electrochemical Science. (2016) 8204–8220. https://doi.org/10.20964/2016.10.17.
M.A. Nasseri, F. Ahrari, B. Zakerinasab, A green biosynthesis of NiO nanoparticles using aqueous extract of Tamarix serotinaand their characterization and application, Applied Organometallic Chemistry. 30 (2016) 978–984. https://doi.org/10.1002/aoc.3530.
B.A. Abbasi, J. Iqbal, T. Mahmood, R. Ahmad, S. Kanwal, S. Afridi, Plant-mediated synthesis of nickel oxide nanoparticles (NiO) via Geranium wallichianum: characterization and different biological applications, Materials Research Express. 6 (2019) 0850a7. https://doi.org/10.1088/2053-1591/ab23e1.
Biplab Kumar Mandal, R. Mandal, Suranjan Sikdar, S. Sarma, A. Srinivasan, Subhajit Roy Chowdhury, B. Das, R. Das, Green synthesis of NiO nanoparticle using Punica granatum peel extract and its characterization for methyl orange degradation, Materials Today Communications. 34 (2023) 105302–105302. https://doi.org/10.1016/j.mtcomm.2022.105302.
R. Yuvakkumar, J. Suresh, A.J. Nathanael, M. Sundrarajan, S.I. Hong, Rambutan (Nephelium lappaceum L.) peel extract assisted biomimetic synthesis of nickel oxide nanocrystals, Materials Letters. 128 (2014) 170–174. https://doi.org/10.1016/j.matlet.2014.04.112.
Downloads
Published
Issue
Section
License
Copyright (c) 2024 Lafia Journal of Scientific and Industrial Research
This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License.
How to Cite
