Effect of Chemical Modifications on the Adsorptive Ability of Palm Kernel Fiber for Indigo Blue Dye

Bolanle Babalola; Samuel Afolabi; Victoria Afolabi; Ibukun Arogundade; Ajibola  Adefisan; Adebanjo  Anifowose

doi:10.62050/ljsir2024.v2n1.284

المؤلفون

Bolanle Babalola
bolanle.babalola@fuoye.edu.ng

Indusrtial Chemistry Department, Federal University Oye-Ekiti, Nigeria
Samuel Afolabi
Indusrtial Chemistry Department, Federal University Oye-Ekiti, Nigeria
Victoria Afolabi
Teaching Service Commission, Ekiti State, Nigeria
Ibukun Arogundade
Indusrtial Chemistry Department, Federal University Oye-Ekiti, Nigeria
Ajibola Adefisan
Indusrtial Chemistry Department, Federal University Oye-Ekiti, Nigeria
Adebanjo Anifowose
Chemistry Department, Osun State University, Osogbo, Nigeria

الكلمات المفتاحية:

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الملخص

This research work investigated the potentials of unmodified Palm Kernel Fibers and its modified forms for the adsorption of Indigo blue dye from aqueous solutions using batch adsorption procedures. Characterization of the fibers were done with the scanning electron microscopy (SEM) and FTIR. Adsorption result showed that maximum uptake of 38.3, 31.0, 33.5 and 14.5 mg/g were respectively obtained for Bleached (BPKF), Acetylated (APKF), Mercerized (MPKF) and Unmodified Palm Kernel Fibers (UPKF) adsorbents at an optimum time of 3 hours. The sorption kinetic obeyed pseudo second order with the bleached adsorbent (BPKF) having the best fit, and at a certain time limit, intra-particle diffusion controlled the process. Data collected from effect of initial concentration experiments were better fit to the Freundlich isotherm. The result from the thermodynamics of the process showed an endothermic process. Increasing adsorbent dosages led to corresponding increase in the quantity of the indigo dye adsorbed by the different adsorbents. This work revealed the potentials of modified palm kernel fibers over the unmodified fiber for effective removal of Indigo blue dye from wastewater.

Dimensions

REFERENCES

Ngaha, M.C.D., Djemmoe, L.G., Njanja, E. and Kenfack, I.T., 2018. Biosorption isotherms and kinetics studies for the removal of 2, 6-dichlorophenolindophenol using palm tree trunk (Elaeis guineensis). Journal of Encapsulation and Adsorption Sciences, 8(3), pp.156-177. https://doi.org/10.4236/jeas.2018.83008

Mane, V.S. and Babu, P.V., 2013. Kinetic and equilibrium studies on the removal of Congo red from aqueous solution using Eucalyptus wood (Eucalyptus globulus) saw dust. Journal of the Taiwan Institute of Chemical Engineers, 44(1), pp.81-88. https://doi.org/10.1016/j.jtice.2012.09.013

Akl, M.A., Youssef, A.M. and Al-Awadhi, M.M., 2013. Adsorption of acid dyes onto bentonite and surfactant-modified bentonite. J. Anal. Bioanalof Delonix regia pods and leaves: removal and recovery of Ni (II) and Cu (II) ions from aqueous solution. Drinking Water Engineering and Science, 13(2), pp.15-27. https://doi.org/10.4172/2155-9872.1000174

Gedam, V.V., Raut, P., Chahande, A. and Pathak, P., 2019. Kinetic, thermodynamics and equilibrium studies on the removal of Congo red dye using activated teak leaf powder. Applied water science, 9(3), p.55. https://doi.org/10.1007/s13201-019-0933-9

Thiyagarajan, E., Saravanan, P., Saranya, P., Gandhi, N.N. and Renganathan, S., 2017. Biosorption of reactive red 2 using positively charged Metapenaeus monoceros shells. Journal of Saudi Chemical Society, 21, pp.S1-S6. https://doi.org/10.1016/j.jscs.2013.05.004

Yagub, M.T., Sen, T.K., Afroze, S. and Ang, H.M., 2014. Dye and its removal from aqueous solution by adsorption: a review. Advances in colloid and interface science, 209, pp.172-184. https://doi.org/10.1016/j.cis.2014.04.002

Abdelwahab, O., Nasr, S.M. and Thabet, W.M., 2017. Palm fibers and modified palm fibers adsorbents for different oils. Alexandria engineering journal, 56(4), pp.749-755. https://doi.org/10.1016/j.aej.2016.11.020

Renu, M.A., Singh, K., Upadhyaya, S. and Dohare, R.K., 2017. Removal of heavy metals from wastewater using modified agricultural adsorbents. Materials Today: Proceedings, 4(9), pp.10534-10538. https://doi.org/10.1016/j.matpr.2017.06.415

Ofomaja, A.E. and Ho, Y.S., 2008. Effect of temperatures and pH on methyl violet biosorption by Mansonia wood sawdust. Bioresource technology, 99(13), pp.5411-5417. https://doi.org/10.1016/j.biortech.2007.11.018

Afolabi, S.O., Babalola, B.M., Babalola, A.O., Afolabi, V.O., Arogundade, I.O. and Adefisan, A.O., 2022. Removal of Indigo Blue Dye from Aqueous Medium (or Industrial Effluent) using Chemically Treated Empty Palm Fruit Bunch Wastes. FUOYE Journal of Pure and Applied Sciences (FJPAS), 7(1), pp.1-19. https://doi.org/10.55518/fjpas.YSEI7794

Said, A.A., Aly, A.A.M., Abd El-Wahab, M.M., Soliman, S.A., Abd El-Hafez, A.A., Helmey, V. and Goda, M.N., 2013. An efficient biosorption of direct dyes from industrial wastewaters using pretreated sugarcane bagasse. Energy and Environmental Engineering, 1(1), pp.10-16. https://doi.org/10.13189/eee.2013.010103

Guler, U.A., Ersan, M., Tuncel, E. and Dügenci, F., 2016. Mono and simultaneous removal of crystal violet and safranin dyes from aqueous solutions by HDTMA-modified Spirulina sp. Process Safety and Environmental Protection, 99, pp.194-206. https://doi.org/10.1016/j.psep.2015.11.006

Ncibi, M.C., Mahjoub, B. and Seffen, M., 2007. Kinetic and equilibrium studies of methylene blue biosorption by Posidonia oceanica (L.) fibres. Journal of hazardous materials, 139(2), pp.280-285. https://doi.org/10.1016/j.jhazmat.2006.06.029

Mwaikambo, L.Y. and Ansell, M.P., 2002. Chemical modification of hemp, sisal, jute, and kapok fibers by alkalization. Journal of applied polymer science, 84(12), pp.2222-2234. https://doi.org/10.1002/app.10460

Adelaja, O.A., Bankole, A.C., Oladipo, M.E. and Lene, D.B., 2019. Biosorption of Hg (II) ions, Congo red and their binary mixture using raw and chemically activated mango leaves. International Journal of Energy and Water Resources, 3(1), pp.1-12. https://doi.org/10.1007/s42108-019-00012-0

Althumayri, K., Guesmi, A., El-Fattah, W. A., Houas, A., Hamadi, N. B. and Shahat, A. (2023). Enhanced adsorption and evaluation of tetracycline removal in an aquatic system by modified silica nanotubes. ACS Omega, 8(7), 6762-6777. https://doi.org/10.1021/acsomega.2c07377

Chen, S., Zhang, J., Zhang, C., Yue, Q., Li, Y. and Li, C. (2010). Equilibrium and kinetic studies of methyl orange and methyl violet adsorption on activated carbon derived from Phragmites australis. Desalination, 252(1-3), 149-156. https://doi.org/10.1016/j.desal.2009.10.010

Annadurai, G., Juang, R.S. and Lee, D.J., 2002. Use of cellulose-based wastes for adsorption of dyes from aqueous solutions. Journal of hazardous materials, 92(3), pp.263-274. https://doi.org/10.1016/S0304-3894(02)00017-1

Etim, U.J., Umoren, S.A. and Eduok, U.K., 2016. Coconut coir dust as a low cost adsorbent for the removal of cationic dye from aqueous solution. Journal of Saudi Chemical Society, 20, pp.S67–S76. https://doi.org/10.1016/j.jscs.2012.09.014

Amalina, F., Abd Razak, A. S., Krishnan, S., Zularisam, A. W. and Nasrullah, M. (2022). The effects of chemical modification on adsorbent performance on water and wastewater treatment-A review. Bioresource Technology Reports, 101259. https://doi.org/10.1016/j.biteb.2022.101259

Boudechiche, N., Mokaddem, H., Sadaoui, Z. and Trari, M., 2016. Biosorption of cationic dye from aqueous solutions onto lignocellulosic biomass (Luffa cylindrica): characterization, equilibrium, kinetic and thermodynamic studies. International Journal of Industrial Chemistry, 7(2), pp.167-180. https://doi.org/10.1007/s40090-015-0066-4

Pinto, T.F., Bezerra, C.W., Silva, D.S., Silva filho, E.C., Vieira, A.P., Airoldi, C., Melo, J.C.D., Silva, H.A. and Santana, S.A., 2016. Sawdust derivative for environmental application: chemistry, functionalization and removal of textile dye from aqueous solution. Anais da Academia Brasileira de Ciências, 88(3), pp.1212-1220. https://doi.org/10.1590/0001-3765201620140656

Lafi, R., Mabrouk, W. and Hafiane, A., 2019. Removal of Methylene blue from saline solutions by adsorption and electrodialysis. Membrane Water Treat, 10, pp.139-148. https://doi.org/10.12989/mwt.2019.10.2.139

Raval, N.P., Shah, P.U. and Shah, N.K., 2016. Adsorptive amputation of hazardous azo dye Congo red from wastewater: a critical review. Environmental Science and Pollution Research, 23(15), pp.14810-14853. https://doi.org/10.1007/s11356-016-6970-0

Salleh, M.A.M., Mahmoud, D.K., Karim, W.A.W.A. and Idris, A., 2011. Cationic and anionic dye adsorption by agricultural solid wastes: A comprehensive review. Desalination, 280(1-3), pp.1-13. https://doi.org/10.1016/j.desal.2011.07.019

Nadaroglu, H., Cicek, S., Onem, H. and Gungor, A.A., 2018. The Investigation of Removing Direct Blue 15 Dye from Wastewater Using Magnetic Luffa sponge NPs. Iron Ores and Iron Oxide Materials, p.207. https://doi.org/10.5772/intechopen.73216

Xiyili, H., Çetintaş, S. and Bingöl, D., 2017. Removal of some heavy metals onto mechanically activated fly ash: Modeling approach for optimization, isotherms, kinetics and thermodynamics. Process Safety and Environmental Protection, 109, pp.288-300. https://doi.org/10.1016/j.psep.2017.04.012