Synsepalum dulcificum extract as green corrosion inhibitor for acid corrosion of mild steel in HCl solution

Authors

Keywords:

Mild steel , Chemical technique , Anticorrosive potential , Adsorption , Synsepalum dulcificum , Flory-Huggins

Abstract

Anticorrosive potential of Synsepalum dulcificum leaf extract on the corrosion of mild steel in HCl solution was investigated using chemical technique. The extract inhibited the deterioration of mild steel in HCl solution and the inhibition efficiency increased with increasing concentration of the extract at 30o C. The results obtained showed that inhibition was as a result of the adsorption of the inhibitor molecule onto mild steel surface and the adsorption obeyed Flory-Huggins adsorption isotherm.

Dimensions

Abiola, O. K., Aliyu, A. O. C., Elemike, E. E. and Adeyemi, O. (2015). Eco-friendly corrosion inhibitor from Tagetes patula L. for aluminium alloy (3SR) in acid fluid used in industrial operations. NISEB J., 15(1), 28-31.

Jianjun, F., Lianjun,W., Jianshang, L., Chang, W. and Yi, L. (2015). The penicillin derivatives as corrosion inhibitors for mild steel in hydrochloric acid solution. Int. J. Electrochem. Sci., 10(10), 8072-8086. https://doi.org/10.1016/S1452-3981(23)11077-7

Abiola, O. K., Aliyu, A. O. C., Philips, A. A. and Ogunsipe, A. O. (2013). The effects of Phyllanthus amarus extract on corrosion and kinetics of corrosion process of aluminium in HCl solution. J. Mater. Envir. Sci., 4(3), 370-373. https://doi.org/10.1016/j.corsci.2009.07.006

Okafor, P. C., Ebenso, E. E. and Ekpe, U. J. (2004). Inhibition of acid corrosion of aluminium by some derivatives of thiosemicarbazone. Bull. Chem. Soci. Ethiop., 18(2), 181-192. https://doi.org/10.4314/bcse.v18i2.61442

Ismail, N., M-Ghazali, M-S., Zulkifli, M-F. R., Umoren, S. A., Kamal, C., Haque, J. and Wan-Nik, W-M. N. (2021). Employing Cymbopogon citratus (lemon grass) as eco-friendly corrosion inhibitor for mild steel in seawater. J. Sustain. Sci. Mgt., 16(3), 71-82. https://doi.org/10.46754/jssm.2021.04.006

Chauhan, D. S., Quraishi, M. A., Wan-Nik, W. B. and Srivastava, V. (2021). Triazines as a potential class of corrosion inhibitors: Present scenario, challenges and future perspectives. J. Mol. Liq. Elsevier, 321 (2021) 114747. https://doi.org/10.1016/j.molliq.2020.114747

Eliboev, I., Berdimurodov, E., Yakhshinorov, K., Abdisattarov, J., Dagdag, O., Berisha, A., Wan-Nik, W. B., Kholikov, A. and Akbarov, K. (2023). Supramolecular corrosion protection: Eco-friendly synthesis and efficacy of a β-cyclodextrin/o-phenylenediamine complex. J. Taiw. Inst. Chem. Engr. Elsevier, 147 (2023) 104944. https://doi.org/10.1016/j.jtice.2023.104944

Abiola, O. K., Odin, E. M., Olowoyo, D. N. and Adeloye, T. A. (2011). Gossipium hirsutum extract as green corrosion inhibitor for aluminium in HCl solution. Bull. Chem. Soci. Ethiop., 25(3), 475-480. https://doi.org/10.4314/bcse.v25i3.68612

Abiola, O. K., Oforka, N. C. and Angaye, S. S. (2004). Corrosion behavior of aluminium in hydrochloric acid (HCl) solution containing mercapto acetic acid. Mater. Lett., 58(27), 3461-3466. https://doi.org/10.1016/j.matlet.2004.06.043

Abiola, O. K., Aliyu, A. O. C. and Suleiman, M. (2017). Anti-corrosive properties of Delonix regia extract on mils steel corrosion in acid fluid for industrial operations. FUW Tren. Sci. Tech. J., 2(18), 489-491.

Abiola, O. K. and James, A. O. (2010). The effects of Aloe vera extract on corrosion and kinetics of corrosion process of zinc in HCl solution. Corros. Sci., 52(2), 661-664. https://doi.org/10.1016/j.corsci.2009.10.026

Abiola, O. K. and Tobun, Y. (2010). Cocos nucifera L. water as green corrosion inhibitor for acid corrosion of aluminium in HCl solution. Chin. Chem. Lett., 21(12), 1449-1452. https://doi.org/10.1016/j.cclet.2010.07.008

Akinbulumo, O. A., Odejobi, O. J. and Odekunle, E. L. (2020). Thermodynamics and adsorption study of the corrosion inhibition of mild steel by Euphorbia heterophylla L. extract in 1.5M HCl. Results Mater., 5, 100074. https://doi.org/10.1016/j.rinma.2020.100074

Amadi, O. K., Akoh, O. U. and Eric, G. C. (2023). Adsorption studies on the inhibitive properties of aqueous extracts of Theobroma cacao leaves on mild steel in 1.0M HCl. Comm. Phys. Sci., 9(3), 269-287.

Dauda, K. T., Atasie, V. N. and Adetimilehin, A. A. (2013). Kinetics of the inhibitory effects of ethanolic extract of Vernonia amygdalina on the corrosion of aluminium in 1.0M HCl. Chem. J., 3(3), 86-89.

Eduok, U. M., Umoren, S. A. and Udoh, A. P. (2012). Synergistic inhibition effects between leaves and stem extracts of Sida acuta and iodide ion for mild steel corrosion 1M H₂SO₄ solutions. Arab. J. Chem., 5(3), 325-337. https://doi.org/10.1016/j.arabjc.2010.09.006

Fekkar, G., Yousfi, F., Elmsellem, H., Aiboudi, M., Ramdani, M., Abdel-Rahman, I., Hammouti, B. and Bouyazza, L. (2020). Eco-friendly Chamaerops humilis L. fruit extract as corrosion inhibitor for mild steel in 1M HCl. Int. J. Corros. Scal. Inhib., 9(2), 446-459. https://doi.org/10.17675/2305-6894-2020-9-2-4

Mohsin, E. A., Husam, M. K. and Rasha, N. A. (2014). Inhibition of copper corrosion in H₂SO₄, NaCl and NaOH solutions by Citrullus colocynthis fruits extract. J. Natur. Sci. Research, 4(17), 60-73.

Obot, I. B., Umoren, S. A. and Obi-Egbedi, N. O. (2011). Corrosion inhibition and adsorption behavior of aluminium by extract of Aningeria robusta in HCl solution: Synergistic effect of iodide ions. J. Mater. Env. Sci., 2(1), 60-71.

Okafor, P. C., Ikpi, M. E., Uwah, I. E., Ebenso, E. E., Ekpu, U. J. and Umoren, S. A. (2008). Inhibitory action of Phyllanthus amarus extract on the corrosion of mild steel in acidic media. Corros. Sci., 50(8), 2310-2317. https://doi.org/10.1016/j.corsci.2008.05.009

Eddy, N. O. (2008). Ethanol extract of Phyllanthus amarus as a green inhibitor for the corrosion of mild steel in H₂SO₄. Portug. Electrochem. Acta, 27(5), 579-589. https://doi.org/10.4152/pea.200905579

Abiola, O. K., John, M. O., Asekunowo, P. O. and Okafor, P. C. (2011). 3-[(4-amino-2-methyl-5-pyrimidinyl) methyl]-5-(2-hydroxyethyl)-4-methyl thiazolium chloride hydrochloride as green corrosion inhibitor of copper in HNO₃ solution and its asorption characteristics. Green Chem. Lett. Rev., 4(3), 273-279. https://doi.org/10.1080/17518253.2011.571716

Abiola, O. K. and Otaigbe, J. O. E. (2009). The effects of Phyllanthus amarus extract on corrosion and kinetics of corrosion process of aluminium in alkaline solution. Corros. Sci., 51(11), 2790-2793. https://doi.org/10.1016/j.corsci.2009.07.006

Sharma, A., Singh, R. T. and Handa, S. S. (1993). Estimation of phyllanthin and hypophyllanthin by high performance liquid chromatograohy in Phyllanthus amarus. J. Phytochem. Analys., 4(5), 226-229. https://doi.org/10.1002/pca.2800040507

Nimibofa, A., Augustus, N. E. and Donbebe, W. (2017). Modelling and interpretation of adsorption isotherms. J. Chem., 2017, 1-12. https://doi.org/10.1155/2017/3039817

front

Published

2024-02-15

How to Cite

Synsepalum dulcificum extract as green corrosion inhibitor for acid corrosion of mild steel in HCl solution. (2024). Lafia Journal of Scientific and Industrial Research, 2(1), 1-4. https://doi.org/10.62050/ljsir2024.v2n1.273

Issue

Volume 2, Issue 1 (April, 2024), Lafia Journal of Scientific and Industrial Research (LJSIR)

Section

Physical Sciences
Copyright & Licensing

Copyright (c) 2024 Lafia Journal of Scientific and Industrial Research

Creative Commons License

This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License.

How to Cite

Synsepalum dulcificum extract as green corrosion inhibitor for acid corrosion of mild steel in HCl solution. (2024). Lafia Journal of Scientific and Industrial Research, 2(1), 1-4. https://doi.org/10.62050/ljsir2024.v2n1.273

Similar Articles

11-20 of 49

You may also start an advanced similarity search for this article.